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Grothe, Hinrich; Willner, Helge

Chlorine Trioxide: Spectroscopic Properties, Molecular Structure, and Photochemical Behavior

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  • Media type: E-Article
  • Title: Chlorine Trioxide: Spectroscopic Properties, Molecular Structure, and Photochemical Behavior
  • Contributor: Grothe, Hinrich; Willner, Helge
  • imprint: Wiley, 1994
  • Published in: Angewandte Chemie International Edition in English
  • Language: English
  • DOI: 10.1002/anie.199414821
  • ISSN: 0570-0833
  • Keywords: Psychiatry and Mental health
  • Origination:
  • Footnote:
  • Description: <jats:p><jats:bold>Though postulated for years, now detected for the first time!</jats:bold> The symmetric ClO<jats:sub>3</jats:sub> radical was synthesized by vacuum flash pyrolysis of chlorine perchlorate and trapped by matrix isolation for UV and IR spectroscopic studies. The OClO bond angle is 113.5±2° and the ClO bond length 150.0±1 pm. The photolysis of ClO<jats:sub>3</jats:sub> yields the unsymmetric isomer OClOO.</jats:p>