Beschreibung:
<jats:title>Abstract</jats:title><jats:p>A cyclocondensation of TIPS‐ethynyl‐substituted diaminoarenes with in situ obtained 4,5‐dibromocyclohexa‐3,5‐diene‐1,2‐dione has led to the synthesis of tetrabromotetraazapentacene (BrTAP). BrTAP is easily reduced to its air‐stable radical anion and electron mobilities >0.56 cm<jats:sup>2</jats:sup> V<jats:sup>−1</jats:sup> s<jats:sup>−1</jats:sup> can be achieved in thin‐film transistors.</jats:p>