• Medientyp: E-Artikel
  • Titel: Collision‐induced liquid secondary‐ion mass spectra of oxytocin derivatives. A study of the influence of modifications in the disulfide bond on the adjacent peptide bond cleavage
  • Beteiligte: Malát, Jan; Ubik, Karel; Lebl, Michal
  • Erschienen: Wiley, 1991
  • Erschienen in: Rapid Communications in Mass Spectrometry
  • Sprache: Englisch
  • DOI: 10.1002/rcm.1290050704
  • ISSN: 0951-4198; 1097-0231
  • Schlagwörter: Organic Chemistry ; Spectroscopy ; Analytical Chemistry
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  • Beschreibung: <jats:title>Abstract</jats:title><jats:p>The influence of the inductive effect of modifications in the disulfide bridge in oxytocin analogs on the cleavage of the neighboring peptidic bond was studied. A correlation between the inductive constant of the group in the disulfide bridge and the particular fragment ion abundance was observed.</jats:p>