Pheromone synthesis, CXXX. Synthesis of (4S,8S)‐ and (4S,8R)‐4,8‐dimethyldecanal, the stereoisomers of the aggregation pheromone of Tribolium castaneum
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Pheromone synthesis, CXXX. Synthesis of (4S,8S)‐ and (4S,8R)‐4,8‐dimethyldecanal, the stereoisomers of the aggregation pheromone of Tribolium castaneum
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<jats:title>Abstract</jats:title><jats:p>(4<jats:italic>S</jats:italic>,8<jats:italic>S</jats:italic>)‐ and (4<jats:italic>S</jats:italic>,8<jats:italic>R</jats:italic>)‐4,8‐Dimethyldecanal (<jats:bold>1</jats:bold>) were synthesized by starting from (<jats:italic>R</jats:italic>)‐citronellic acid (<jats:bold>2a</jats:bold>), methyl (<jats:italic>S</jats:italic>)‐3‐hydroxy‐2‐methylpropanoate (<jats:bold>3a</jats:bold>), and (<jats:italic>S</jats:italic>)‐2‐methyl‐1‐butanol (<jats:bold>4a</jats:bold>).</jats:p>