Pheromone synthesis, CXLVII. – Synthesis of (1R,3S,6R,9S,10S)‐9,10‐Epoxytetrahydroedulan, the Main Component of the Hairpencil Secretion of Male Danaid Butterfly Euploea klugii
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Titel:
Pheromone synthesis, CXLVII. – Synthesis of (1R,3S,6R,9S,10S)‐9,10‐Epoxytetrahydroedulan, the Main Component of the Hairpencil Secretion of Male Danaid Butterfly Euploea klugii
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<jats:title>Abstract</jats:title><jats:p>The natural and (+)‐enantiomer of 9,10‐epoxytetrahydroedulan <jats:bold>1</jats:bold>, (1<jats:italic>R</jats:italic>,3<jats:italic>S</jats:italic>,6<jats:italic>R</jats:italic>,9<jats:italic>S</jats:italic>,10<jats:italic>S</jats:italic>)‐9,10‐epoxy‐1,3,7,7‐tetramethyl‐2‐oxabicyclo[4.4.0]decane, the main component of the hairpencil secretion of <jats:italic>Euploea klugii</jats:italic>, was synthesized via (−)‐dihydroedulan II (<jats:bold>2</jats:bold>) by starting from (<jats:italic>S</jats:italic>)‐2,4,4‐trimethyl‐2‐cyclohexen‐1‐ol (<jats:bold>D</jats:bold>).</jats:p>