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Medientyp:
E-Artikel
Titel:
Diterpenoid Total Synthesis, XXX. Synthesis of the Racemic Form of Tripterifordin, a Novel Anti‐HIV Diterpene Lactone from Tripterygium wilfordii
Beschreibung:
<jats:title>Abstract</jats:title><jats:p>The pentacyclic diterpene ketone (±)‐<jats:bold>3</jats:bold>, which had been prepared by a total synthesis from naphthalene, was methylenated and hydrated to give (±)‐tripterifordin [(±)‐<jats:bold>1</jats:bold>], the racemate of a new kaurane‐type diterpene lactone with anti‐HIV activity recently isolated from the roots of <jats:italic>Tripterygium wilfordii</jats:italic>.</jats:p>